# Carbonate chemistry over a timecourse in pH drift experiments # S. Dudgeon, J. Kubler (CSU) # version: 2018-02-07 # ========================= trial sal_insitu temp_insitu ------------------------- 6 33.2 20 ========================= ID ALK pH_t0 pH_t2 pH_t6 pH_t20 pH_t24 pH_t30 t0_DIC_x_1e06 t2_DIC_x_1e06 t6_DIC_x_1e06 t20_DIC_x_1e06 t24_DIC_x_1e06 t30_DIC_x_1e06 t0_CO2_x_1e06 t2_CO2_x_1e06 t6_CO2_x_1e06 t20_CO2_x_1e06 t24_CO2_x_1e06 t30_CO2_x_1e06 t0_HCO3_x_1e06 t2_HCO3_x_1e06 t6_HCO3_x_1e06 t20_HCO3_x_1e06 t24_HCO3_x_1e06 t30_HCO3_x_1e06 t0_CO3_x_1e06 t2_CO3_x_1e06 t6_CO3_x_1e06 t20_CO3_x_1e06 t24_CO3_x_1e06 t30_CO3_x_1e06 ------------------------- SW-A-1-1 2181.72 7.9762 nd nd nd 8.4662 8.4662 1976.016746 nd nd nd 1678.748216 1678.748216 15.14346654 nd nd nd 3.616340072 3.616340072 1813.038712 nd nd nd 1337.984366 1337.984366 147.8345674 nd nd nd 337.1475099 337.1475099 SW-A-2-1 2181.72 7.9762 nd nd nd 8.4162 8.4162 1976.016746 nd nd nd 1714.99268 1714.99268 15.14346654 nd nd nd 4.23662033 4.23662033 1813.038712 nd nd nd 1397.01581 1397.01581 147.8345674 nd nd nd 313.7402502 313.7402502 SW-A-2-2 2181.72 7.9762 nd nd nd 8.4162 8.4162 1976.016746 nd nd nd 1714.99268 1714.99268 15.14346654 nd nd nd 4.23662033 4.23662033 1813.038712 nd nd nd 1397.01581 1397.01581 147.8345674 nd nd nd 313.7402502 313.7402502 SW-A-3-1 2181.72 7.9762 nd nd nd 8.4462 8.4562 1976.016746 nd nd nd 1693.368662 1686.077978 15.14346654 nd nd nd 3.854199105 3.73361384 1813.038712 nd nd nd 1361.808126 1349.929764 147.8345674 nd nd nd 327.7063364 332.4146002 SW-A-3-2 2181.72 7.9762 nd nd nd 8.4062 8.4162 1976.016746 nd nd nd 1722.113688 1714.99268 15.14346654 nd nd nd 4.371256307 4.23662033 1813.038712 nd nd nd 1408.601177 1397.01581 147.8345674 nd nd nd 309.1412542 313.7402502 SW-A-4-1 2173.01 7.8056 nd nd nd 8.3956 8.4156 2039.446741 nd nd nd 1722.188829 1708.041463 23.63709481 nd nd nd 4.498645249 4.226334845 1910.626831 nd nd nd 1414.697292 1391.700161 105.1828151 nd nd nd 302.9928916 312.114967 SW-A-4-2 2173.01 7.8056 nd nd nd 8.4956 8.5156 2039.446741 nd nd nd 1649.787477 1634.863331 23.63709481 nd nd nd 3.275712195 3.069594912 1910.626831 nd nd nd 1296.84333 1272.514798 105.1828151 nd nd nd 349.6684352 359.2789385 SW-A-5-1 2173.01 7.8056 nd nd nd 8.4356 8.4556 2039.446741 nd nd nd 1693.717165 1679.226095 23.63709481 nd nd nd 3.968535217 3.724584335 1910.626831 nd nd nd 1368.396686 1344.805843 105.1828151 nd nd nd 321.3519438 330.6956674 SW-A-5-2 2173.01 7.8056 nd nd nd 8.4856 8.4856 2039.446741 nd nd nd 1657.200601 1657.200601 23.63709481 nd nd nd 3.383241235 3.383241235 1910.626831 nd nd nd 1308.924933 1308.924933 105.1828151 nd nd nd 344.8924266 344.8924266 SW-A-6-1 2173.01 7.8056 nd nd nd 8.3556 8.3856 2039.446741 nd nd nd 1749.915542 1729.193172 23.63709481 nd nd nd 5.089586782 4.640456439 1910.626831 nd nd nd 1459.702322 1426.075357 105.1828151 nd nd nd 285.1236332 298.4773587 SW-A-6-2 2173.01 7.8056 nd nd nd 8.2856 8.3056 2039.446741 nd nd nd 1796.449071 1783.424978 23.63709481 nd nd nd 6.288073706 5.922808665 1910.626831 nd nd nd 1534.968257 1513.942839 105.1828151 nd nd nd 255.1927408 263.5593305 SW-A-7-1 2181.1 7.5949 nd nd nd 8.3349 8.3749 2119.865937 nd nd nd 1770.962758 1743.571114 40.41957107 nd nd nd 5.442756908 4.815660614 2011.284356 nd nd nd 1488.335061 1443.901765 68.16201069 nd nd nd 277.1849399 294.8536884 SW-A-7-2 2181.1 7.5949 nd nd nd 8.2249 8.2549 2119.865937 nd nd nd 1841.790268 1823.161053 40.41957107 nd nd nd 7.549762955 6.914270317 2011.284356 nd nd nd 1602.562925 1572.635698 68.16201069 nd nd nd 231.6775803 243.6110856 SW-A-8-1 2181.1 7.5949 nd nd nd 8.3849 8.4349 2119.865937 nd nd nd 1736.598056 1701.036114 40.41957107 nd nd nd 4.669123542 3.993318659 2011.284356 nd nd nd 1432.574249 1374.724721 68.16201069 nd nd nd 299.3546839 322.3180745 SW-A-8-2 2181.1 7.5949 nd nd nd 8.2449 8.2849 2119.865937 nd nd nd 1829.429664 1804.007636 40.41957107 nd nd nd 7.120680585 6.326128391 2011.284356 nd nd nd 1582.717047 1541.77066 68.16201069 nd nd nd 239.5919364 255.9108471 SW-A-9-1 2181.1 7.5949 nd nd nd 8.3149 8.3349 2119.865937 nd nd nd 1784.344973 1770.962758 40.41957107 nd nd nd 5.782227271 5.442756908 2011.284356 nd nd nd 1509.999949 1488.335061 68.16201069 nd nd nd 268.5627963 277.1849399 A-A-1-1 2411.9 8.0054 nd nd nd 8.3554 8.3654 2176.830244 nd nd nd 1955.99848 1948.565825 15.52461221 nd nd nd 5.69201384 5.520732072 1987.936628 nd nd nd 1631.727837 1619.490653 173.3690036 nd nd nd 318.5786298 323.5544397 A-A-2-1 2411.9 8.0054 nd nd nd 8.1354 8.1554 2176.830244 nd nd nd 2104.062469 2091.89162 15.52461221 nd nd nd 10.84250654 10.24642633 1987.936628 nd nd nd 1872.886538 1853.336151 173.3690036 nd nd nd 220.333425 228.3090435 A-A-2-2 2411.9 8.0054 nd nd nd 8.3354 8.3554 2176.830244 nd nd nd 1970.694833 1955.99848 15.52461221 nd nd nd 6.048561857 5.69201384 1987.936628 nd nd nd 1655.89922 1631.727837 173.3690036 nd nd nd 308.7470516 318.5786298 A-A-3-1 2411.9 8.0054 nd nd nd 8.3054 8.3254 2176.830244 nd nd nd 1992.302952 1977.95661 15.52461221 nd nd nd 6.619986791 6.234044676 1987.936628 nd nd nd 1691.37107 1667.829631 173.3690036 nd nd nd 294.3118953 303.8929345 A-A-3-2 2411.9 8.0054 nd nd nd 8.3054 8.3254 2176.830244 nd nd nd 1992.302952 1977.95661 15.52461221 nd nd nd 6.619986791 6.234044676 1987.936628 nd nd nd 1691.37107 1667.829631 173.3690036 nd nd nd 294.3118953 303.8929345 A-A-4-1 2428.55 7.8382 nd nd nd 8.2482 8.2682 2271.440378 nd nd nd 2046.742456 2033.028605 24.3446331 nd nd nd 7.898564235 7.44754919 2121.216559 nd nd nd 1769.00854 1746.606835 125.8791861 nd nd nd 269.8353518 278.9742206 A-A-4-2 2428.55 7.8382 nd nd nd 8.2982 8.3082 2271.440378 nd nd nd 2011.985242 2004.847269 24.3446331 nd nd nd 6.813315264 6.612680446 2121.216559 nd nd nd 1712.143889 1700.432164 125.8791861 nd nd nd 293.0280383 297.8024242 A-A-5-1 2428.55 7.8382 nd nd nd 8.1882 8.2082 2271.440378 nd nd nd 2086.330313 2073.396155 24.3446331 nd nd nd 9.398686263 8.87301112 2121.216559 nd nd nd 1833.364964 1812.394772 125.8791861 nd nd nd 243.5666626 252.1283713 A-A-5-2 2428.55 7.8382 nd nd nd 8.1182 8.1382 2271.440378 nd nd nd 2129.514969 2117.507889 24.3446331 nd nd nd 11.46121182 10.83468812 2121.216559 nd nd nd 1902.883999 1883.641238 125.8791861 nd nd nd 215.1697582 223.0319632 A-A-6-1 2428.55 7.8382 nd nd nd 8.4282 8.4782 2271.440378 nd nd nd 1914.732294 1875.042035 24.3446331 nd nd nd 4.577983529 3.907358999 2121.216559 nd nd nd 1551.87237 1486.158364 125.8791861 nd nd nd 358.281941 384.9763119 A-A-6-2 2428.55 7.8382 nd nd nd 8.1682 8.2182 2271.440378 nd nd nd 2099.000217 2066.830464 24.3446331 nd nd nd 9.951575374 8.620002542 2121.216559 nd nd nd 1853.845819 1801.727756 125.8791861 nd nd nd 235.2028226 256.4827057 A-A-7-1 2412.05 7.6305 nd nd nd 8.0805 8.1105 2335.488433 nd nd nd 2136.258613 2118.984193 40.97511377 nd nd nd 12.6402011 11.62806698 2213.104612 nd nd nd 1924.13597 1896.659191 81.40870769 nd nd nd 199.4824419 210.6969348 A-A-7-2 2412.05 7.6305 nd nd nd 8.3705 8.4105 2335.488433 nd nd nd 1944.882711 1914.505293 40.97511377 nd nd nd 5.435485513 4.80326801 2213.104612 nd nd nd 1613.318514 1563.214572 81.40870769 nd nd nd 326.1287119 346.4874529 A-A-8-1 2412.05 7.6305 nd nd nd 8.1505 8.1805 2335.488433 nd nd nd 2095.033859 2076.379054 40.97511377 nd nd nd 10.39039907 9.53998251 2213.104612 nd nd nd 1858.292197 1828.22378 81.40870769 nd nd nd 226.3512624 238.6152912 A-A-8-2 2412.05 7.6305 nd nd nd 8.1205 8.1605 2335.488433 nd nd nd 2113.095286 2088.88153 40.97511377 nd nd nd 11.30702397 10.09978946 2213.104612 nd nd nd 1887.252842 1848.392065 81.40870769 nd nd nd 214.5354203 230.3896755 A-A-9-1 2412.05 7.6305 nd nd nd 8.0205 8.0505 2335.488433 nd nd nd 2169.069467 2152.950354 40.97511377 nd nd nd 14.90229567 13.72981101 2213.104612 nd nd nd 1975.763467 1950.501706 81.40870769 nd nd nd 178.4037046 188.7188372 E-A-1-1 2679.12 8.0547 nd nd nd 8.1547 8.1547 2397.449224 nd nd nd 2334.352576 2334.352576 15.12992628 nd nd nd 11.45440684 11.45440684 2170.294086 nd nd nd 2068.494543 2068.494543 212.0252112 nd nd nd 254.403626 254.403626 E-A-2-1 2679.12 8.0547 nd nd nd 8.1747 8.1747 2397.449224 nd nd nd 2320.874749 2320.874749 15.12992628 nd nd nd 10.82251957 10.82251957 2170.294086 nd nd nd 2046.492488 2046.492488 212.0252112 nd nd nd 263.5597412 263.5597412 E-A-2-2 2679.12 8.0547 nd nd nd 8.1047 8.1147 2397.449224 nd nd nd 2366.789811 2360.445602 15.12992628 nd nd nd 13.1789458 12.81673124 2170.294086 nd nd nd 2121.106364 2110.858164 212.0252112 nd nd nd 232.5045009 236.7707065 E-A-3-1 2679.12 8.0547 nd nd nd 8.0847 8.0947 2397.449224 nd nd nd 2379.26491 2373.062818 15.12992628 nd nd nd 13.93072595 13.55020889 2170.294086 nd nd nd 2141.191565 2131.21746 212.0252112 nd nd nd 224.1426186 228.2951488 E-A-3-2 2679.12 8.0547 nd nd nd 8.0947 8.0947 2397.449224 nd nd nd 2373.062818 2373.062818 15.12992628 nd nd nd 13.55020889 13.55020889 2170.294086 nd nd nd 2131.21746 2131.21746 212.0252112 nd nd nd 228.2951488 228.2951488 E-A-4-1 2653.98 7.886 nd nd nd 8.086 8.056 2464.677855 nd nd nd 2355.36935 2373.447895 23.53710557 nd nd nd 13.74595545 14.9300121 2289.469331 nd nd nd 2119.125644 2148.037875 151.6714183 nd nd nd 222.4977505 210.4800083 E-A-4-2 2653.98 7.886 nd nd nd 7.916 7.856 2464.677855 nd nd nd 2449.879536 2478.971334 23.53710557 nd nd nd 21.75234658 25.45388922 2289.469331 nd nd nd 2267.189853 2310.659353 151.6714183 nd nd nd 160.9373355 142.858091 E-A-5-1 2653.98 7.886 nd nd nd 7.926 7.756 2464.677855 nd nd nd 2444.830067 2523.336782 23.53710557 nd nd nd 21.18525418 32.92070724 2289.469331 nd nd nd 2259.516173 2373.837203 151.6714183 nd nd nd 164.1286403 116.5788721 E-A-5-2 2653.98 7.886 nd nd nd 7.876 7.776 2464.677855 nd nd nd 2469.497114 2514.834322 23.53710557 nd nd nd 24.16091964 31.28335094 2289.469331 nd nd nd 2296.652223 2362.082389 151.6714183 nd nd nd 148.6839716 121.4685813 E-A-6-1 2653.98 7.886 nd nd nd 7.896 7.816 2464.677855 nd nd nd 2459.802487 2497.291958 23.53710557 nd nd nd 22.92795582 28.23108127 2289.469331 nd nd nd 2282.165371 2337.272167 151.6714183 nd nd nd 154.7091602 131.7887094 E-A-6-2 2653.98 7.886 nd nd nd 7.906 7.826 2464.677855 nd nd nd 2454.870032 2492.787579 23.53710557 nd nd nd 22.33314285 27.51196289 2289.469331 nd nd nd 2274.739237 2330.791105 151.6714183 nd nd nd 157.7976519 134.4845114 E-A-7-1 2652.49 7.6832 nd nd nd 7.9132 7.8732 2551.500368 nd nd nd 2449.872267 2469.417527 39.55096192 nd nd nd 21.9009654 24.32428284 2411.786309 nd nd nd 2268.01036 2297.321726 100.1630967 nd nd nd 159.9609415 147.7715189 E-A-7-2 2652.49 7.6832 nd nd nd 7.8332 7.7732 2551.500368 nd nd nd 2488.086412 2514.596094 39.55096192 nd nd nd 26.98913787 31.4899521 2411.786309 nd nd nd 2324.720723 2362.401855 100.1630967 nd nd nd 136.3765515 120.7042863 E-A-8-1 2652.49 7.6832 nd nd nd 7.7932 7.7532 2551.500368 nd nd nd 2505.946677 2523.070922 39.55096192 nd nd nd 29.91841036 33.13719192 2411.786309 nd nd nd 2350.283706 2374.091637 100.1630967 nd nd nd 125.7445605 115.842093 E-A-8-2 2652.49 7.6832 nd nd nd 7.9032 7.8832 2551.500368 nd nd nd 2454.844245 2464.615902 39.55096192 nd nd nd 22.48532438 23.69665738 2411.786309 nd nd nd 2275.521443 2290.176027 100.1630967 nd nd nd 156.8374779 150.7432179 E-A-9-1 2652.49 7.6832 nd nd nd 7.8832 7.8832 2551.500368 nd nd nd 2464.615902 2464.615902 39.55096192 nd nd nd 23.69665738 23.69665738 2411.786309 nd nd nd 2290.176027 2290.176027 100.1630967 nd nd nd 150.7432179 150.7432179 SW-NA-380-1 2188.62 7.9784 nd nd nd 7.7784 7.7484 1981.456707 nd nd nd 2064.695698 2075.654672 15.10327405 nd nd nd 25.53721183 27.57383372 1817.409851 nd nd nd 1938.8993 1953.794701 148.9435824 nd nd nd 100.2591854 94.2861375 SW-NA-380-2 2174.82 7.974 nd nd nd 7.784 7.754 1970.569324 nd nd nd 2049.303806 2060.2738 15.18356304 nd nd nd 25.0103028 27.00753317 1808.653912 nd nd nd 1923.537799 1938.503963 146.7318488 nd nd nd 100.7557041 94.76230387 SW-NA-540-1 2173.01 7.8086 nd nd nd 7.7586 7.7286 2038.30503 nd nd nd 2056.862374 2067.546315 23.45472328 nd nd nd 26.66935543 28.7877567 1909.027078 nd nd nd 1934.613858 1948.900193 105.8232283 nd nd nd 95.57916056 89.85836581 SW-NA-540-2 2173.01 7.8025 nd nd nd 7.7425 7.7125 2040.622583 nd nd nd 2062.635582 2073.152943 23.82690802 nd nd nd 27.78765369 29.98766844 1912.271107 nd nd nd 1942.377563 1956.250543 104.5245679 nd nd nd 92.47036467 86.91473152 SW-NA-700-1 2181.19 7.5947 nd nd nd 7.4647 7.4547 2120.018085 nd nd nd 2160.033194 2163.058303 40.4413351 nd nd nd 55.67583061 57.04921618 2011.440821 nd nd nd 2052.808701 2055.566148 68.13592831 nd nd nd 51.54866203 50.44293809 SW-NA-700-2 2181.01 7.5951 nd nd nd 7.4751 7.4551 2119.713786 nd nd nd 2156.704347 2162.756785 40.39781803 nd nd nd 54.27634385 56.98891022 2011.127866 nd nd nd 2049.709718 2055.285353 68.18810186 nd nd nd 52.7182855 50.48252218 A-NA-380-1 2412.12 8.0048 nd nd nd 7.9048 7.8848 2177.346406 nd nd nd 2226.211132 2235.310332 15.55131791 nd nd nd 20.31205162 21.4088328 1988.60705 nd nd nd 2063.172624 2076.704794 173.188038 nd nd nd 142.7264567 137.1967056 A-NA-380-2 2411.68 8.006 nd nd nd 7.926 7.906 2176.313904 nd nd nd 2215.914231 2225.241388 15.49794781 nd nd nd 19.2016234 20.24409975 1987.265848 nd nd nd 2047.951761 2061.960035 173.5501074 nd nd nd 148.7608462 143.037253 A-NA-540-1 2425.93 7.8412 nd nd nd 7.7712 7.7612 2267.645699 nd nd nd 2296.596278 2300.559703 24.12916679 nd nd nd 28.89742229 29.64512142 2117.015806 nd nd nd 2157.947524 2163.390949 126.500726 nd nd nd 109.7513313 107.5236321 A-NA-540-2 2431.17 7.8352 nd nd nd 7.7652 7.7552 2275.232861 nd nd nd 2304.044952 2307.990952 24.56185602 nd nd nd 29.40858889 30.16855579 2125.411159 nd nd nd 2165.987577 2171.382311 125.2598461 nd nd nd 108.6487862 106.4400851 A-NA-700-1 2411.48 7.6285 nd nd nd 7.5485 7.5485 2335.629026 nd nd nd 2362.995104 2362.995104 41.16998386 nd nd nd 50.19121378 50.19121378 2213.413079 nd nd nd 2244.447615 2244.447615 81.04596345 nd nd nd 68.35627543 68.35627543 A-NA-700-2 2412.62 7.6324 nd nd nd 7.5524 7.5524 2335.381743 nd nd nd 2362.817051 2362.817051 40.79126911 nd nd nd 49.73522816 49.73522816 2212.834799 nd nd nd 2244.119036 2244.119036 81.75567528 nd nd nd 68.96278745 68.96278745 E-NA-380-1 2665.55 8.0561 nd nd nd 8.0061 7.9761 2384.07777 nd nd nd 2412.939174 2429.455676 14.99314136 nd nd nd 17.17875827 18.62303141 2157.617276 nd nd nd 2203.299539 2229.113339 211.4673527 nd nd nd 192.4608773 181.7193055 E-NA-380-2 2692.69 8.0533 nd nd nd 8.0133 7.9833 2410.825893 nd nd nd 2434.157044 2450.946859 15.26750323 nd nd nd 17.02417493 18.45811148 2182.980196 nd nd nd 2219.973797 2246.306634 212.5781941 nd nd nd 197.1590722 186.182114 E-NA-540-1 2655.02 7.8878 nd nd nd 7.8378 7.8278 2464.792796 nd nd nd 2488.40385 2492.968493 23.43578332 nd nd nd 26.69565769 27.39527194 2289.081466 nd nd nd 2323.926563 2330.544452 152.2755464 nd nd nd 137.7816298 135.028769 E-NA-540-2 2652.94 7.8842 nd nd nd 7.8242 7.8142 2464.560564 nd nd nd 2492.604552 2497.098707 23.6388155 nd nd nd 27.62909734 28.35099552 2289.852383 nd nd nd 2331.033267 2337.491759 151.069365 nd nd nd 133.942188 131.2559519 E-NA-700-1 2650.93 7.6829 nd nd nd 7.6029 7.6029 2550.094629 nd nd nd 2580.657224 2580.657224 39.55713529 nd nd nd 48.29533307 48.29533307 2410.497069 nd nd nd 2447.862057 2447.862057 100.0404244 nd nd nd 84.49983445 84.49983445 E-NA-700-2 2654.05 7.6835 nd nd nd 7.6035 7.5935 2552.905966 nd nd nd 2583.510588 2587.225269 39.5447743 nd nd nd 48.28104366 49.49208552 2413.075311 nd nd nd 2450.520976 2454.807999 100.2858809 nd nd nd 84.70856837 82.92518466